Phase Content and Thermoelectric Properties of Optimized Thermoelectric Structures Based on the Ag-Pb-Sb-Te System


Horichok I., AHISKA R., Freik D., Nykyruy L., Mudry S., Matkivskiy O., ...Daha Fazla

JOURNAL OF ELECTRONIC MATERIALS, cilt.45, sa.3, ss.1576-1583, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 45 Sayı: 3
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1007/s11664-015-4122-9
  • Dergi Adı: JOURNAL OF ELECTRONIC MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1576-1583
  • Anahtar Kelimeler: Lead telluride, doping, solid solutions, LAST, thermoelectric properties, HIGH-PERFORMANCE, MICROSTRUCTURES, NANOSTRUCTURES, AGPBMSBTE2+M
  • Gazi Üniversitesi Adresli: Evet

Özet

Results of x-ray studies and measurements of thermoelectric parameters (Seebeck coefficient S, specific electrical conductivity sigma, and thermal conductivity chi) of materials based on lead telluride, such as PbTe, PbTe:Sb, PbTe-Sb2Te3, Pb18Ag1Sb1Te20, Pb18Ag2Te20, and PbTe-Ag2Te, are presented. It was found that PbTe:Sb (with 0.3 at.% Sb) as well as Pb18Ag1Sb1Te20 and Pb18Ag2Te20 systems have the highest thermoelectric figure of merit values. In the case of PbTe:Sb, this is due to a significant increase of the electrical conductivity. In the cases of Pb18Ag1Sb1Te20 and Pb18Ag2Te20, it is due to an increase of the Seebeck coefficient and a significant reduction in the thermal conductivity compared with pure PbTe.