Lubricants, cilt.14, sa.2, 2026 (SCI-Expanded, Scopus)
In this study, boron carbide (B4C), hexagonal boron nitride (hBN), holy super graphene (HSG), and hybrid (B4C+hBN+HSG) nano-additives were added to SAE 15W-40 diesel engine oil at a range of 0.03–0.24 g per 30 mL of oil, and reciprocating tribological tests were conducted on a GG25 (EN-GJL-250) gray cast iron-based diesel piston surface in contact with an Al2O3 ball (Ø6 mm) at a load of 20 N, a sliding distance of 500 m, and a temperature of 75 °C. XRD analysis showed that the dominant phase on the piston surface was the α-Fe matrix and that no significant new phase had formed. The results obtained revealed that the nano-additive effect is strongly dependent on both the additive type and the additive level. At a low level (0.03 g/30 mL) of B4C additive, the average COF decreased by approximately 19%, while at a low level (0.03 g/30 mL) of hBN additive, this decrease amounted to approximately 54%. In the HSG additive, at the highest level (0.24 g/30 mL), the coefficient of friction (COF) decreased to ≈0.032, achieving a friction reduction of approximately 75% compared to the base oil. In the hybrid oil series, COF values remained in the range of approximately 0.082–0.087 at all additive levels and were generally 25–28% lower than those of the base oil. SEM/EDS examinations showed that a tribofilm with high carbon content formed in the HSG-additive oils, while a tribofilm layer containing C, B, and N elements together formed in the hybrid-additive oils. Overall, it was concluded that selecting the appropriate additive type and level can reduce friction and wear losses at the piston interface, thereby contributing to engine efficiency by extending the life of engine components and limiting friction-induced energy losses.