Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation

Sendil, Kivilcim; Ozgun, H.; Ustun, Ebru

doi:10.1155/2016/3518102

Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation

Atıf İçin Kopyala

Sendil K., Ozgun H. B., Ustun E.

JOURNAL OF CHEMISTRY, cilt.2016, 2016 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 2016
Basım Tarihi: 2016
Doi Numarası: 10.1155/2016/3518102
Dergi Adı: JOURNAL OF CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Gazi Üniversitesi Adresli: Evet

Özet

Two new mild oxidizing agents 1,1,3,3-tetramethylguanidinium fluorochromate (TMGFC) and 1,1,3,3-tetramethylguanidinium chlorochromate (TMGCC) were prepared in high yields by reacting tetramethylguanidine with CrO3 and related acid. These reagents are suitable to oxidize various primary and secondary alcohols and oximes to the corresponding carbonyl compounds under solvent-free conditions and microwave irradiation.