FT-IR Spectroscopic and Some Thermal Properties of Hofmann-Type Clathrate and Transition Metal Complexes of 2-Aminothiazole

Tufan Y., Kilicer C., Kormali F.

ASIAN JOURNAL OF CHEMISTRY, cilt.22, sa.9, ss.6791-6797, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 22 Sayı: 9
  • Basım Tarihi: 2010
  • Dergi Adı: ASIAN JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.6791-6797
  • Anahtar Kelimeler: Infrared spectrum, Hofmann type calthrates, 2-A minothiazole(atz), Benzene, Thermal decomposition, METHYL-4 AMINO-2 THIAZOLE, AROMATIC GUEST SYSTEMS, LE SPECTRE INFRAROUGE, VIBRATIONAL-SPECTRA, DIALCOYLES, ETUDE
  • Gazi Üniversitesi Adresli: Evet

Özet

In this study, new Hofmann type transition metal complexes of the form M(2-aminothiazole)(2)NRCN)(4) (M = Mn, Fe, Co, Ni, Cu, Zn, Cd) and Cd(2-aminothiazole)(2)Ni(CN)(4)center dot C(6)H(6), Hofmann type clathrate, have been prepared in powder form and their infrared spectra and some thermal decomposition properties of the clathrate are reported. The spectral and thermal data show that the structures of these complexes and the clathrate are analogous with related Hofmann type complexes. The observed v(C-N) wave numbers of the complexes are in good agrement with Irving-Williams natural stability series.