Infrared spectroscopic studies of the Hofmann-daon-type clathrates: M(1,8-diaminooctane)Ni(CN)(4)center dot G (M = Co, Ni or Cd; G = 1,2-dichlorobenzene or 1,4-dichlorobenzene)

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Sertbakan T., Saglam S., Kasap E., Kantarci Z.

JOURNAL OF MOLECULAR STRUCTURE, vol.482, pp.75-79, 1999 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 482
  • Publication Date: 1999
  • Doi Number: 10.1016/s0022-2860(99)00020-4
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.75-79
  • Keywords: Hofmann-type clathrates, tetracyanonickelate, 1,8-diaminooctane, infrared spectra, dichlorobenzene, MOLECULE INCLUSION-COMPOUNDS, CRYSTAL-STRUCTURES, 1,5-DIAMINOPENTANE
  • Gazi University Affiliated: Yes


New Hofmann-daon-type clathrates of the form M(1,8-diaminooctane)Ni(CN)(4). G (M = Co, Ni or Cd; G = 1,2-dichlorobenzene or 1,4-dichlorobenzene) were prepared in powder form and their infrared spectra are reported. The spectral features suggest that these compounds are similar in structure to the en-Hofmann-type clathrates and their structure consists of corrugated polymeric layers of {M-Ni(CN)(4)}(infinity) with the 1,8-diaminooctane spaned between two metal (M) atoms, of the consecutive two layers. (C) 1999 Elsevier Science B.V. All rights reserved.