Investigation of host-guest interactions in the Hofmann-dabn-type clathrates: M(1,4-diaminobutane)Ni(CN)4·1.5G (M = Co or Ni, G = benzene derivatives)


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Saglam S., Sertbakan T., Kasap E., Kantarci Z.

Journal of Molecular Structure, cilt.482-483, ss.69-74, 1999 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Özet
  • Cilt numarası: 482-483
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1016/s0022-2860(99)00019-8
  • Dergi Adı: Journal of Molecular Structure
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.69-74
  • Anahtar Kelimeler: 1,4-diaminobutane, Benzene derivatives, Hofmann-type clathrates, Infrared spectra, Tetracyanonickelate
  • Gazi Üniversitesi Adresli: Evet

Özet

Infrared spectra of M(1,4-diaminobutane)Ni(CN)4·1.5G (M = Co or Ni; G = chlorobenzene, m-xylene, or p-xylene) are reported. The spectral data suggest that the compounds are similar in host structure to that of Hofmann- type clathrates M(1,4-diaminobutane)Ni(CN)4·1.5C6H6 (M = Mn, Fe, Co, Ni or Cd).