An infrared spectroscopic study on the Hofmann- and en-T-d-type clathrates: Mn(NH3)(2)Zn(CN)(4).2benzene and Mn(ethylenediamine)Zn(CN)(4).2benzene


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Kantarci Z., Bayrak C., Kasap E.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.39, ss.103-108, 2001 (SCI-Expanded) identifier identifier

Özet

Infrared spectra of Mn(NH3)(2)Zn(CN)(4). 2C(6)H(6) and Mn(ethylenediamine)Zn(CN)(4). 2C(6)H(6) are reported. The spectral data suggest that these compounds are similar in structure to Hofmann-T-d-type and the en-T-d-type clathrates, respectively. There is good evidence for H-bonding from ammonia N-H to benzene as a pi to sigma H-bond.