An infrared spectroscopic study on the Hofmann- and en-T-d-type clathrates: Mn(NH3)(2)Zn(CN)(4).2benzene and Mn(ethylenediamine)Zn(CN)(4).2benzene

Kantarci, Z; Bayrak, C; Kasap, ERGÜN

doi:10.1023/a:1008169222179

An infrared spectroscopic study on the Hofmann- and en-T-d-type clathrates: Mn(NH3)(2)Zn(CN)(4).2benzene and Mn(ethylenediamine)Zn(CN)(4).2benzene

Kantarci Z., Bayrak C., Kasap E.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.39, ss.103-108, 2001 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 39
Basım Tarihi: 2001
Doi Numarası: 10.1023/a:1008169222179
Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Sayfa Sayıları: ss.103-108
Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
Gazi Üniversitesi Adresli: Evet

Özet

Infrared spectra of Mn(NH3)(2)Zn(CN)(4). 2C(6)H(6) and Mn(ethylenediamine)Zn(CN)(4). 2C(6)H(6) are reported. The spectral data suggest that these compounds are similar in structure to Hofmann-T-d-type and the en-T-d-type clathrates, respectively. There is good evidence for H-bonding from ammonia N-H to benzene as a pi to sigma H-bond.