Simultaneous determination of cadmium and zinc using a fiber optic device and fluorescence spectrometry
TALANTA, cilt.51, sa.4, ss.693-699, 2000 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 51 Sayı: 4
- Basım Tarihi: 2000
- Doi Numarası: 10.1016/s0039-9140(99)00327-6
- Dergi Adı: TALANTA
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.693-699
- Anahtar Kelimeler: cadmium, zinc, optode, fluorescence spectrometry, ANTHRYLAZAMACROCYCLE CONJUGATE PROBES, SPECTROSCOPY
- Gazi Üniversitesi Adresli: Evet
Özet
A reservoir type of optode is described for simultaneous and remote determination of Cd and Zn using [9-(1',4',7', 10',13'-pentaazacyclopentadecyl)methylanthracene] as the fluorophore. Simultaneous analysis was achieved by the significant perturbation in the fluorescence spectrum of the Cd-ligand complex while the Zn complex only results in enhancement in the fluorescence intensity as compared to ligand alone. The ion permeability of several membranes were examined; Nafion and cellophane were used for the construction of the optode. Using the optode constructed with cellophane, for 20 min immersion time, the 3-s detection limits were found to be 4.5 mu g l(-1) for Cd and 0.6 mu g l(-1) for Zn. (C) 2000 Elsevier Science B.V. All rights reserved.