Simultaneous determination of cadmium and zinc using a fiber optic device and fluorescence spectrometry

Ertas N., Akkaya E., Ataman O.

TALANTA, cilt.51, sa.4, ss.693-699, 2000 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 51 Sayı: 4
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1016/s0039-9140(99)00327-6
  • Dergi Adı: TALANTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.693-699
  • Anahtar Kelimeler: cadmium, zinc, optode, fluorescence spectrometry, ANTHRYLAZAMACROCYCLE CONJUGATE PROBES, SPECTROSCOPY
  • Gazi Üniversitesi Adresli: Evet

Özet

A reservoir type of optode is described for simultaneous and remote determination of Cd and Zn using [9-(1',4',7', 10',13'-pentaazacyclopentadecyl)methylanthracene] as the fluorophore. Simultaneous analysis was achieved by the significant perturbation in the fluorescence spectrum of the Cd-ligand complex while the Zn complex only results in enhancement in the fluorescence intensity as compared to ligand alone. The ion permeability of several membranes were examined; Nafion and cellophane were used for the construction of the optode. Using the optode constructed with cellophane, for 20 min immersion time, the 3-s detection limits were found to be 4.5 mu g l(-1) for Cd and 0.6 mu g l(-1) for Zn. (C) 2000 Elsevier Science B.V. All rights reserved.