A new, safe and convenient procedure for reduction of naphthalene and anthracene: synthesis of tetralin in a one-pot reaction
JOURNAL OF CHEMICAL RESEARCH-S, sa.11, ss.752-753, 2003 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 2003
- Doi Numarası: 10.3184/030823403322863201
- Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.752-753
- Anahtar Kelimeler: reductions, sodium, naphthalene, anthracene, tert-butyl alcohol, METAL-AMMONIA REDUCTION, AROMATIC-COMPOUNDS, DOUBLE-BOND, PRODUCTS
- Gazi Üniversitesi Adresli: Evet
Özet
Reduction of naphthalene and anthracene with sodium and tert-butyl alcohol gave 1,4-dihydronaphthalene and 9,10-dihydroanthracene respectively in high yields at room temperature (r.t.) as the sole products. The synthesis of tetralin from naphthalene was carried out in a one-pot reaction via 1,4-dihydronaphthalene. The reduced products were easily isolated.