Vibrational spectroscopic study on pyrimidine metal(II) tetracyanometalate complexes


Bahat M., Yurdakul Ş.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.58, sa.5, ss.933-939, 2002 (SCI-Expanded) identifier identifier identifier

Özet

The results of an infrared and Raman spectroscopic study are reported for seven new metal(II): pyrimidine tetracyanonickelate complexes, M(pyr)(2)Ni(CN)(4) [where (pyr) == pyrimidine; M = Mn, Fe, Co, Zn, Ni, Cu or Cd] and an IR spectroscopic study is presented for new cadmium pyrimidine tetracyanometalate complex. Cd(pyr)(2)Cd(CTq)(4), The spectral data suggest that the first seven compounds belong to the Hofmann-type and the last compound belongs to the Hofmann-T-d-type of complexes. (C) 2002 Elsevier Science B.V. All rights reserved.