Vibrational spectroscopic study on pyrimidine metal(II) tetracyanometalate complexes


Bahat M., Yurdakul S.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.58, ss.933-939, 2002 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 58 Konu: 5
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1016/s1386-1425(01)00562-5
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Sayfa Sayıları: ss.933-939

Özet

The results of an infrared and Raman spectroscopic study are reported for seven new metal(II): pyrimidine tetracyanonickelate complexes, M(pyr)(2)Ni(CN)(4) [where (pyr) == pyrimidine; M = Mn, Fe, Co, Zn, Ni, Cu or Cd] and an IR spectroscopic study is presented for new cadmium pyrimidine tetracyanometalate complex. Cd(pyr)(2)Cd(CTq)(4), The spectral data suggest that the first seven compounds belong to the Hofmann-type and the last compound belongs to the Hofmann-T-d-type of complexes. (C) 2002 Elsevier Science B.V. All rights reserved.