Vibrational spectroscopic investigations of M(imidazole)(2)Ni(CN)(4)center dot 2 dioxane clathrates


Tufan Y., Karacan N. , Davies J.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.33, sa.2, ss.149-154, 1999 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 33 Konu: 2
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1023/a:1007941906692
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Sayfa Sayıları: ss.149-154

Özet

Four new clathrates of the formula M(lm)(2)Ni(CN)(4). 2 . Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and their FT-IR and laser-Raman spectra are reported for the first time. These clathrates are analogues to the previously reported classical Hofmann type clathrates except for the copper clathrate. The Cu clathrate has different spectral features in comparison with its analogues due to the Jahn-Teller effect.