Vibrational spectroscopic investigations of M(imidazole)(2)Ni(CN)(4)center dot 2 dioxane clathrates

Tufan Y., Karacan N., Davies J.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.33, sa.2, ss.149-154, 1999 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 2
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1023/a:1007941906692
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.149-154
  • Anahtar Kelimeler: Hofmann-type clathrate, metal-imidazole complexes, dioxane inclusion compounds, IR and Raman spectra, INFRARED-SPECTRA, NORMAL-MODES, IMIDAZOLE, ASSIGNMENT, COMPLEXES
  • Gazi Üniversitesi Adresli: Evet

Özet

Four new clathrates of the formula M(lm)(2)Ni(CN)(4). 2 . Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and their FT-IR and laser-Raman spectra are reported for the first time. These clathrates are analogues to the previously reported classical Hofmann type clathrates except for the copper clathrate. The Cu clathrate has different spectral features in comparison with its analogues due to the Jahn-Teller effect.