EFFICIENT DETERMINATION AND PESTICIDE CONTROL BY MEANS OF IMMOBILIZATION OF ACETYLCHOLINESTERASE


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Hasanoğlu Özkan E., Kurnaz Yetim N., Gümüş M., Sarı N., Dişli A.

MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, vol.36, pp.119-128, 2017 (Peer-Reviewed Journal) identifier

  • Publication Type: Article / Article
  • Volume: 36
  • Publication Date: 2017
  • Doi Number: 10.20450/mjcce.2017.1178
  • Journal Name: MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING
  • Journal Indexes: Science Citation Index Expanded
  • Page Numbers: pp.119-128
  • Keywords: acetylcholinesterase, nanoparticle, hazardous materials, tetrazole, immobilization, 5-SUBSTITUTED 1H-TETRAZOLES, ANTIMICROBIAL ACTIVITY, NANOPARTICLES, CATALYST, DERIVATIVES, GLUCOSE

Abstract

Supports involving tetrazole (o/m/p-F-Tet-1H) were prepared to detect pesticides. This novel tetrazole including fluorine in different positions was attached to nanoparticles (2AEPS-(o/m/p-F-Tet-1H)) by a condensation method. Primarily, the tetrazole derivatives were characterized by H-1-NMR, C-13-NMR and LC-MS. Then, nanoparticles were prepared by a condensation method in non-aqueous medium and characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, gel permeation chromatography. The enzymatic properties of immobilized acetylcholinesterase (AChE) were investigated for the determination of phosmet. This research is the first example.