Square wave voltammetric determination of pencycuron fungicide and application to commercial formulation

Acer S., Demir E., İnam R.

JOURNAL OF FOOD MEASUREMENT AND CHARACTERIZATION, cilt.14, sa.4, ss.2099-2107, 2020 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 14 Sayı: 4
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1007/s11694-020-00457-6
  • Dergi Adı: JOURNAL OF FOOD MEASUREMENT AND CHARACTERIZATION
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Agricultural & Environmental Science Database, CAB Abstracts, Compendex, Food Science & Technology Abstracts, Veterinary Science Database
  • Sayfa Sayıları: ss.2099-2107
  • Anahtar Kelimeler: Pencycuron, Voltammetry, Determination, Glassy carbon electrode, LIQUID-CHROMATOGRAPHY, GAS-CHROMATOGRAPHY, MASS-SPECTROMETRY, CARBON, PESTICIDES, WATER, HERBICIDE, ELECTRODE, BEHAVIOR, ORGANOPHOSPHORUS
  • Gazi Üniversitesi Adresli: Evet

Özet

Pencycuron is a rather new, non-systemic protective fungicide of the phenylurea class, which is used in the treatment of diseases on various crops and whose residues must therefore, be determined with reliable analytical methods. A rapid, sensitive and reproducible square wave stripping and cyclic voltammetric method applied for the first time for the determination of pencycuron fungicide and it has exhibited a well-defined anodic peak at + 1140 mV (vs Ag/AgCl). A linear relationship has been constructed with a dynamic working range of 0.2-10.0 mg/L on a glassy carbon electrode with a limit of determination and limit of quantification of 0.05 mg/L and 0.17 mg/L, respectively. The simultaneous determination of pencycuron and diethofencarb performed with the relative standard deviations of 4.26% and 1.90% and with the relative errors of 6.00% and + 2.00%, respectively. According to the analytical estimations made in the commercial formulation, pencycuron was obtained as 20.21 +/- 0.32 with a relative standard deviation of 1.58 % and the relative error of + 1.05%, which means that the accuracy and precision is quite good.