{4-methyl-2-[(2-oxidobenzylidene)amino]phenolato(2-)-N,O,O'}(piperidine-N)nickel(II)


Atakol O., Kenar A., Ercan F., Sari M., Yagbasan R.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.52, ss.1881-1884, 1996 (SCI-Expanded) identifier identifier

Özet

In the title compound, [Ni(C14H11NO2)(C5H11N)], coordination geometry at the Ni atom was found to be a slightly distorted square-planar polygon formed by the O, N and O' donor atoms of the tridentate ligand and the N donor atom of the monodentate ligand [O-Ni-N 86.6(2)-95.9 (3)degrees, Ni-O 1.810(5) and 1.833(4), Ni-N 1.862(6) and 1.933(7) Angstrom]. The diamagnetic properties of the complex, determined by the Gouy method, are in agreement with the planar coordination.