Azo Dye Removal Using Free and Immobilized Fungal Biomasses: Isotherms, Kinetics and Thermodynamic Studies

BAYRAMOĞLU G., Yilmaz M.

FIBERS AND POLYMERS, cilt.19, sa.4, ss.877-886, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 19 Sayı: 4
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1007/s12221-018-7875-y
  • Dergi Adı: FIBERS AND POLYMERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.877-886
  • Anahtar Kelimeler: Composite biomass, Reactive Yellow 86, Adsorption, Isotherms, Kinetics, Thermodynamics, CRYSTAL VIOLET ADSORPTION, AQUEOUS-SOLUTION, METHYLENE-BLUE, WASTE-WATER, DEGRADATION, ACID, EQUILIBRIUM, BIOSORPTION, EFFICIENCY, LACCASE
  • Gazi Üniversitesi Adresli: Evet

Özet

In this study, Lentinus concinnus biomass was immobilized in polyvinyl alcohol/polyethyleneoxide hydrogels (PVA/PEO; referred as composite biomass) and used for removal of Reactive Yellow 86 dye (RY-86) from aqueous solution using free fungal biomass as a control system. The free fungal and composite fungal biomasses were characterized using ATR-FTIR, SEM and analytical methods. FTIR studies of the adsorbent preparations show that carboxylate, hydroxyl and amine groups should be involved in adsorption of the RY-86 dye. The adsorption of RY-86 dye on these adsorbents increased as the initial concentration of RY-86 dye in the medium increased up to 200 mg/l. The maximum RY-86 dye adsorption for the free fungal and composite fungal biomasses, was obtained as 190.2 and 87.6, respectively, using 200 mg/l initial dye concentration, at 25 A degrees C, and at pH 5.0 with 2.0 h contact. The equilibrium data were well described with the Freundlich and Temkin isotherm models. The adsorption of RY-86 dye was fitted best by the pseudo second-order kinetic model. Thermodynamic parameters (Delta GA degrees, Delta HA degrees, and Delta SA degrees) showed that RY-86 dye adsorption on both adsorbents were spontaneous process.