Infrared and Raman spectroscopic study of the Hofmann-type clathrates M(1,7-diaminoheptane)Ni(CN)4·G (M = Ni or Co; G = chlorobenzene, m-xylene or naphthalene)


Kasap E. , Ozbay A. , Ozcelik S.

Journal of Molecular Structure, ss.425-430, 1997 (SCI Expanded İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası:
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1016/s0022-2860(96)09551-8
  • Dergi Adı: Journal of Molecular Structure
  • Sayfa Sayıları: ss.425-430

Özet

Two new Hofmann-diaminoheptane-type clathrates of the form M(1,7-diaminoheptane) Ni(CN)4·G (M = Ni or Co; G = chlorobenzene, m-xylene or naphthalene) have been prepared in powder form. Their spectral data were compared with those of the corresponding host. Their structure consists of corrugated polymeric layers of {M-Ni(CN)4} ∞ with the 1,7-diaminoheptane molecules bound directly to the metal (M).