Infrared and Raman spectroscopic study of the Hofmann-type clathrates M(1,7-diaminoheptane)Ni(CN)4·G (M = Ni or Co; G = chlorobenzene, m-xylene or naphthalene)


Kasap E. , Ozbay A. , Ozcelik S.

Journal of Molecular Structure, pp.425-430, 1997 (Journal Indexed in SCI Expanded) identifier identifier

  • Publication Type: Article / Abstract
  • Volume:
  • Publication Date: 1997
  • Doi Number: 10.1016/s0022-2860(96)09551-8
  • Title of Journal : Journal of Molecular Structure
  • Page Numbers: pp.425-430

Abstract

Two new Hofmann-diaminoheptane-type clathrates of the form M(1,7-diaminoheptane) Ni(CN)4·G (M = Ni or Co; G = chlorobenzene, m-xylene or naphthalene) have been prepared in powder form. Their spectral data were compared with those of the corresponding host. Their structure consists of corrugated polymeric layers of {M-Ni(CN)4} ∞ with the 1,7-diaminoheptane molecules bound directly to the metal (M).