Vibrational spectroscopic investigation of the Hofmann-type clathrates: M(piperidine)(2)Ni(CN)(4).G(M=Co, Ni or Cu; G = benzene derivatives)


Yurdakul E., Gulluoglu M.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.40, no.3, pp.231-237, 2001 (SCI-Expanded) identifier identifier

Abstract

Infrared spectra of M(pipcridine)(2)Ni(CN)(4).0.5G (M=Co, Ni or Cu; G= chlorobenzene, 1,2-dichlorobenzene or 1,3-dichlorobenzene; M=Co or Ni; G=1,4-dichlorobenzene) compounds are reported, The piperidine molecules in the host permit the inclusion of bulky guest molecules. The spectral features suggest that the compounds are similar in structure to the Hofmann-type clathrates.