Vibrational spectroscopic investigation of the Hofmann-type clathrates: M(piperidine)(2)Ni(CN)(4).G(M=Co, Ni or Cu; G = benzene derivatives)


Yurdakul E., Gulluoglu M.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.40, no.3, pp.231-237, 2001 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 40 Issue: 3
  • Publication Date: 2001
  • Doi Number: 10.1023/a:1011829513218
  • Title of Journal : JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Page Numbers: pp.231-237

Abstract

Infrared spectra of M(pipcridine)(2)Ni(CN)(4).0.5G (M=Co, Ni or Cu; G= chlorobenzene, 1,2-dichlorobenzene or 1,3-dichlorobenzene; M=Co or Ni; G=1,4-dichlorobenzene) compounds are reported, The piperidine molecules in the host permit the inclusion of bulky guest molecules. The spectral features suggest that the compounds are similar in structure to the Hofmann-type clathrates.