Chemical shifts of K alpha and K beta(1,3) X-ray emission spectra for oxygen compounds of Ti, Cr, Fe, Co, Cu with WDXRF


Oez E. , Baydas E., ŞAHİN Y.

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, cilt.279, ss.529-537, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 279 Konu: 2
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1007/s10967-007-7313-5
  • Dergi Adı: JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • Sayfa Sayıları: ss.529-537

Özet

Chemical shifts and full widths at half maximum intensity (FWHM) of K alpha and K beta(1,3) X-ray emission lines and differences of full widths at half maximum intensity (Delta FHWM) using metallic element as reference for these emission lines were measured for oxygen compounds of elements in the range 22a parts per thousand currency signZa parts per thousand currency sign29 with a Wavelength-Dispersive X-Ray Fluorescence Spectrometer (WDXRF). It was also found larger chemical shifts and FWHM for K beta(1,3) lines than those of K alpha ones. It should be noted that the magnitude of the chemical shifts increases with increasing number of ligand atom.